Densities, Viscosities and Apparent Molar Volumes of KClO3 in Water and Some Aqueous Electrolyte Solutions at Different Temperatures

International Journal of Applied Chemistry

© 2016 by SSRG - IJAC Journal

Volume 3 Issue 3

Year of Publication : 2016

Authors : Arun B. Nikumbh, Meenakshi V. Rathi

10.14445/23939133/IJAC-V3I5P102

How to Cite?

Arun B. Nikumbh, Meenakshi V. Rathi, "Densities, Viscosities and Apparent Molar Volumes of KClO3 in Water and Some Aqueous Electrolyte Solutions at Different Temperatures," SSRG International Journal of Applied Chemistry, vol. 3,  no. 3, pp. 1-6, 2016. Crossref, https://doi.org/10.14445/23939133/IJAC-V3I5P102

Abstract:

The densities and viscosities of KClO3 in water and aqueous solutions of some electrolytes like potassium chloride, potassium nitrate and ammonium nitrate have been measured at the temperatures (298.15, 303.15, 308.15,and 313.15)K.Six different concentrations ranging from 0.0065 to 0.0365 M were prepared. The apparent molar volumes ( ) and viscosity B coefficients of these salts are obtained. The limiting apparent molar volumes ( ) and experimental slopes ( ) derived from the Masson’s equation have been interpreted in terms of ion-solvent and ion-ion interactions, respectively. The viscosity data have been analyzed using the Jones-Dole equation, and the derived parameters B and A have also been interpreted in terms of ion-solvent and ion-ion interactions. The structure making/breaking capacities of these salts investigated have been discussed.

Keywords:

KClO3, density, viscosity, B-coefficient, apparent molar volumes.

References:

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