Computation of Dielectric constant and loss factor of 1-ethyl-3-methylimidazolium chloride (emim)
International Journal of Applied Physics |
© 2020 by SSRG - IJAP Journal |
Volume 7 Issue 1 |
Year of Publication : 2020 |
Authors : Lubis Satzen, Samson D. Yusuf, Abdulmumini Z. Loko, Lucas W. Lumbi |
How to Cite?
Lubis Satzen, Samson D. Yusuf, Abdulmumini Z. Loko, Lucas W. Lumbi, "Computation of Dielectric constant and loss factor of 1-ethyl-3-methylimidazolium chloride (emim)," SSRG International Journal of Applied Physics, vol. 7, no. 1, pp. 110-116, 2020. Crossref, https://doi.org/10.14445/23500301/IJAP-V7I1P116
Abstract:
Ionic liquid has special characteristics such as wide electrochemical windows electrochemical stability, tunable physiochemical properties etc. They are potentially excellent candidate for environmentally sound, green electrolytes in batteries. Because of its unique properties, it is essential to gain information about their dielectric properties. The Cole-Cole relaxation equation was derived and the values for the dielectric constant and loss factor of 1-ethyl-3-methylimidazolium chloride (emim) were determined. The computation was done within the frequency of 0.1GHz to 10GHz and temperature between 50c to 550c. The result obtained shows that the dielectric constant and loss factor of 1-ethyl-3-methylimidazolium chloride (emim) were higher at low frequency (i.e. F = 0.1GHz) and decreases as the frequency increases. The dielectric constant also increases with increase in the temperature except at 0.1GHz. The loss factor was small for all frequencies and temperatures. This may be due to the fact that the ionic liquids consumed less energy when subjected to an applied field. However it is advisable to use such IL in high frequency because the dielectric constant is low at high frequency.
Keywords:
Dielectric Constant, Loss Factor, Frequency, Temperature, Cole-Cole Method
References:
[1] M. Freemantle, “An introduction to ionic liquids”, New York, USA: RSC publishing, Pp. 347-215, 2009.
[2] M. Gaune – Escard, and K. R. Seddon, “Molten salts and ionic liquids”, Never the Twain viley, 2010.
[3] R. Regers, and K. Seddon, “Ionic liquid: fundamental progress, challenges and opportunities, properties and structure”, ACS Symp. Ser., American Chemical Society, Washington DC., vol. 901(12), pp. 278-419, 2005.
[4] N. Plechkova, and K. Seddon, “Applications of ionic liquids in the chemical industry”, Chemical Society Reviews, vol. 37(1), pp. 123, 2008.
[5] R. D. Rogers, N. V. Plechkova, and K. R. Seddon, “Ionic liquids: From knowledge of application”, ACS Symp. Ser., American Chemical Society, Washington DC., vol.1030, 2009.
[6] T. Fischer, A. Sethi, T. Welton, and J. Woolf, “Dielectric reactions in room temperature ionic liquids”, Tetrahedron Lett., vol. 40(1), pp. 793-796, 1999.
[7] M. Galinski, A. Lewandowski, and I. Stepniak, “Ionic liquids as electrolytes”, Electrochem. Acta., vol. 51(1), pp. 5567-5580, 2006.
[8] W. Hough, M. Smiglak, H. Rodriguez, R. Swwatlok, S. Spear, D. Daly, J. Pemak, J. Grisel, R. Carliss, M. Soutullo, J. Davis, and R. Rogers, “The third evolution of ionic liquids: active pharmaceutical ingredients”, New J. Chem., vol. 31(1), pp. 1429-1436, 2007.
[9] K. Fujita, N. Nakamura, K. Igarashi, M. Samejima, and H. Ohno, “Biocatalytic oxidation of cellulose in an hydrated ionic liquids”, Green Chem., vol. 11(1), pp. 351-354, 2009.
[10] Z. Fei, T. J. Geldbach, D. Zhao, and P. J. Dyson, “From dysfunction to bis-function on the design and applications of functionalized ionic liquids”, Chemistry Eur. Journal, vol. 12(1), pp. 2122-2130, 2006.
[11] D. M. Guan, Y. Cheng, T. Wang, and J. Tang, “Dielectric Properties of Mashed Potatoes relevant to microwave and radiofrequency Pasteurization and Sterilization Processes”, J. Food Sci., vol. 69(1), pp. 30-37, 2004.
[12] P. Cserjesi, A. Gollei, B. K. Belafi, and L. Gubicza, “Dielectric properties of ionic liquids proposed to be used in batteries”, MSc. Eng. University of pamonia, Hungary, 2009.
[13] W. Herman, “The static dielectric constant of ionic liquids”, International Journal of Physical Chemistry and Chemical Physics, vol. 220(10), 2009.
[14] T. J. Ikyumbur, E. N. Asagha, E. C. Hemba, and J. A. Bash, “Dielectric properties of 1-ethyl-3-methyl-imidazolium tetra fluoroborate (EMIM-BF4) using Cole-Cole Relaxation model”, Physical Sc. International Journal, vol. 13(3), 2017a.
[15] T. J. Ikyumbur, M. Y. Onimisi, S. G. Abdu, E. C. Hemba, and Z. J. Kurji, “Optimization in the computation of Dielectric constant of methanol using Debye Relaxation Method”, British Journal of Applied Sc. and Technology, vol. 19(1), 2017b.
[16] M. Y. Onimisi, and T. J. Ikyumbur, “Computation of Dielectric constant and loss factor of water and dimethylsulphoxide from 0.1to13GHz”, Scientific Review, vol. 1(4), pp. 79-85, 2015a.
[17] M. Y. Onimisi, and T. J. Ikyumbur, “Comparative Analysis of Dielectric constant and loss factor of pure Butan-1-ol and Ethanol”, American Journal of Condensed Matter Physics, vol. 5(3), pp. 69-75, 2015b.