Study of Density, Molar Volume, X-Ray Diffraction and Infrared Spectra of Phosphate Glasses

International Journal of Applied Physics
© 2021 by SSRG - IJAP Journal
Volume 8 Issue 2
Year of Publication : 2021
Authors : Abdulkarim Z. Khalf, Ebtihal G . Khadr, Ayoub S .Karim, Mohammed H . Abbas, Manaf A . Hassan

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Abdulkarim Z. Khalf, Ebtihal G . Khadr, Ayoub S .Karim, Mohammed H . Abbas, Manaf A . Hassan, "Study of Density, Molar Volume, X-Ray Diffraction and Infrared Spectra of Phosphate Glasses," SSRG International Journal of Applied Physics, vol. 8,  no. 2, pp. 16-20, 2021. Crossref, https://doi.org/10.14445/23500301/IJAP-V8I2P103

Abstract:

Glasses with compositions
X% V2O5 – (50-X)% BaO – (50)% P2O5
X% V2O5 – (50-X)% CaO – (50)% P205
X% V2O5 – (50-X)% MgO – (50)% P2O5
Where x = 5,10,15,and 20 mol%) The result of investigations of density and molar volume ,x-ray diffraction (XRD) and infrared spectra are reported . The density measurements show that the values of the density increasing with the increasing of V2O5 content in the glass systems . From the infrared absorption spectra , it is found that the addition of BaO , CaO and MgO does not introduce any new absorption band in the infrared spectrum of the glass system .

Keywords:

Optical properties, Oxide Glasses, Absorption Edge, lead phosphate oxide glasses,

References:

[1] Yaacob, S. N. S., Sahar, M. R., Sazali, E. S., & Sulhadi, S. (2019). The Polarizability and Optical Characteristics of Zinc Phosphate Glasses Doped Terbium Embedded with Copper Oxide Nanoparticles. In Solid State Phenomena (Vol. 290, pp. 35-40). Trans Tech Publications Ltd.
[2] Ravikumar, R. V. S. S. N., Komatsu, R., Ikeda, K., Chandrasekhar, A. V., Reddy, B. J., Reddy, Y. P., & Rao, P. S. (2003). EPR and optical studies on transition metal doped LiRbB4O7 glasses. Journal of Physics and Chemistry of Solids, 64(2) 261-264.
[3] Ibrahim, S., & Marzouk, M. A. (2017). Structural characteristics and electrical conductivity of vanadium-doped lithium ultraphosphate glasses. Silicon, 9(3) 403-410.
[4] Ravikumar, R. V. S. S. N., Chandrasekhar, A. V., Ramamoorthy, L., Reddy, B. J., Reddy, Y. P., Yamauchi, J., & Rao, P. S. (2004). Spectroscopic studies of transition metal doped sodium phosphate glasses. Journal of alloys and compounds, 364(1-2) 176-179.
[5] Brow, R. K., & Tallant, D. R. (1997). Structural design of sealing glasses. Journal of Non-Crystalline Solids, 222, 396-406.
[6] Ray, N. H., NH, R., & CJ, L. (1973). Oxide glasses of very low softening point. I. Preparation and properties of some lead phosphate glasses.
[7] Sidek, H. A. A., Collier, I. T., Hampton, R. N., Saunders, G. A., & Bridge, B. (1989). Electrical conductivity and dielectric constant of samarium phosphate glasses. Philosophical Magazine B, 59(2) 221-232.
[8] Wazer, J. R. V. (1950). Structure and properties of the condensed phosphates. II. A theory of the molecular structure of sodium phosphate glasses1. Journal of the American Chemical Society, 72(2) 644-647.
[9] Flory, P. J. (1953). Principles of polymer chemistry. Cornell University Press.
[10] Prasad, P. S., Rao, V. H., Babu, M. M., Rao, P. V., Raju, G. N., & Laxmikanth, C. (2015). Spectroscopic investigations of the PbO–MoO3–P2O5: V2O5 glass system. Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B, 56(4) 169-174.
[11] Anderson, G. W., & Luehrs Jr, F. U. (1968). Structural Characterization of and Phase Separation in Vanadate Glasses. Journal of Applied Physics, 39(3) 1634-1638.
[12] Kundu, V., Dhiman, R. L., Maan, A. S., & Goyal, D. R. (2008). Structural and Physical Properties of Fe2 O3-B2 O3-V2 O5 Glasses. Advances in Condensed Matter Physics, 2008.
[13] Kundu, R. S., Dhankhar, S., Punia, R., Sharma, S., & Kishore, N. (2013). ZnCl2 modified physical and optical properties of barium tellurite glasses. Transactions of the Indian Ceramic Society, 72(3) 206-210.
[14] Tasheva, T., & Dimitrov, V. (2017). Senthesis, Optical properties and structure of NiO-BaO-V 2 O 5 glasses. Journal of Chemical Technology & Metallurgy, 52(2).
[15] Richard, A. (1971). Nyquist and Ronald O Kagel. IR Spectra of Inorganic Compounds (New York and London: Academic Press.Aynur, B.k., & Hassan, M.A., J .Education science to be published
[16] Dogra, M., Singh, K. J., Kaur, K., & Anand, V. (2018). Gamma ray shielding properties at 129· 5 MBq and structural investigations of the Bi2O3–B2O3–K2O–Li2O–V2O5 glass system. Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B, 59(6) 293-300.
[17] Prasad, P. S., Rao, V. H., Babu, M. M., Rao, P. V., Raju, G. N., & Laxmikanth, C. (2015). Spectroscopic investigations of the PbO–MoO3–P2O5: V2O5 glass system. Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B, 56(4) 169-174.
[18] Obed, S. A., & Hassan, M. A. (2016). A Study of Infrared Spectra of Some Semiconducting Oxide Glasses. kirkuk university journal for scientific studies, 11(3).
[19] Lakshmikantha, R., Rajaramakrishna, R., Anavekar, R. V., & Ayachit, N. H. (2012). Characterization and structural studies of vanadium doped lithium–barium–phosphate glasses. Canadian journal of physics, 90(3) 235-239.
[20] Dhyghm A. Ibrahim Najat A. Dahham, Manaf A. Hassan (2020) Optical Properties of Lead-Phosphate Glasses International Journal of Applied Physics (SSRG-IJAP) V7I3P103
[21] Mohammed H . Abbas Manaf A . Hassan Optical Properties of Phosphate Glasses International Journal of Applied Physics (SSRG-IJAP) V7I3P105