A Study of DSC and Raman Spectroscopy of Phosphate- Vanadate Semiconducting Oxide Glasses Containing BaO, MgO and CaO

International Journal of Applied Physics

© 2021 by SSRG - IJAP Journal

Volume 8 Issue 2

Year of Publication : 2021

Authors : Faten M . Junaid, Manaf A . Hassan

10.14445/23500301/IJAP-V8I2P105

How to Cite?

Faten M . Junaid, Manaf A . Hassan, "A Study of DSC and Raman Spectroscopy of Phosphate- Vanadate Semiconducting Oxide Glasses Containing BaO, MgO and CaO," SSRG International Journal of Applied Physics, vol. 8,  no. 2, pp. 30-36, 2021. Crossref, https://doi.org/10.14445/23500301/IJAP-V8I2P105

Abstract:

Glasses having compositions (50)% P2O5–(50-x)%BaO– (x)%V2O5, (50)% P2O5– (50-X)%CaO–(X)%V2O5, (50)% P2O5– (50-X)%MgO–(X)%V2O5 ,where (x=5,10,15 and 20 mol%) were prepared by the normal melt quenching technique. The thermal parameters, such as the glass transition temperature (Tg), The onset of crystallization temperature (Tc), thermal stability (S) and the thermodynamic fragility (F) we determined. It has been found that the glass transition temperature (Tg) for (P2O5-CaO-V2O5) and (P2O5-MgO-V2O5) increase with increasing (V2O5) content in the glass matrix but decreases with increasing (V2O5) in the glass (P2O5-BaO-V2O5). The Raman spectroscopy in the range (200-4200)cm-1 was used to prove the changes in the structure of the prepared glasses. Strong peak has shown in all glass samples in the range (420-440) cm-1 which may be due to symmetrical stretching or bending vibration.

Keywords:

DSC, Glass transition temperature, Oxide Glasses, Raman spectroscopy, V2O5.

References:

[1] Wilder Jr, James A., Glasses and Glass Ceramics for Sealing to Aluminum Alloys. Journal of Non-Crystalline Solids, 38 (1980) 879–84 Elsevier.
[2] Proulx, P. P., et al., Raman and Low Frequency Raman Spectroscopy of Lead, Zinc and Barium Metaphosphate Glasses Doped with Eu3+ Ions, Journal of Physics: Condensed Matter, 6(1) (1994) 275 IOP Publishing.
[3] Musinu, A., et al., Structural Properties of Lead-Iron Phosphate Glasses by X-Ray Diffraction, Journal of Non-Crystalline Solids, 122(1) (1990) 52–58 Elsevier.
[4] Liu, H. S., and T. S. Chin. ,Low Melting PbO-ZnO-P2O5 Glasses. Part 2. A Structural Study by Raman Spectroscopy and MAS-NMR., Physics and Chemistry of Glasses, 38(3) (1997) 123–31.
[5] Kitamura, Naoyuki, et al. ,Optical Properties of Fluorine-Substituted Zinc Bismuth Phosphate Glasses., Journal of Non-Crystalline Solids, 357(3) (2011) 1188–92 Elsevier.
[6] Lai, Y. M., et al. ,Raman Spectra Study of Iron Phosphate Glasses with Sodium Sulfate., Journal of Molecular Structure, 1013 (2012) 134–37 Elsevier.
[7] Pisarski, Wojciech A., et al. ,Structure and Spectroscopy of Rare Earth–Doped Lead Phosphate Glasses., Journal of Alloys and Compounds, 587 (2014) 90–98 Elsevier.
[8] Kiani, Azadeh, et al. ,Structural Characterization and Physical Properties of P2O5–CaO–Na2O–TiO2 Glasses by Fourier Transform Infrared, Raman and Solid-State Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopies., Acta Biomaterialia, 8(1) (2012) 333–40 Elsevier.
[9] Tiwari, Babita, et al. National Symposium on Science and Technology of Glass and Glass-Ceramics: Extended Abstracts. (2006).
[10] Eltabey, M. M., et al. ,Synthesis and Characterization of Bismuth Phosphate Nanoparticle in Glass Matrix., Journal of Thermal Analysis and Calorimetry, 128(2) (2017) 755–64.
[11] Kamalaker, V., et al. ,Raman Spectroscopy, Thermal and Optical Properties of TeO2–ZnO–Nb2O5–Nd2O3 Glasses., Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 89 (2012) 149–54 Elsevier.
[12] Sahar, M. R., et al. ,Spectroscopic Studies of TeO 2–ZnO–Er 2 O 3 Glass System., Journal of Materials Science, 42(3) (2007) 824–27
[13] Gedikoğlu, Nuşik, et al. ,Investigating the Influence of Transition Metal Oxides on Temperature Dependent Optical Properties of PbCl2–TeO2 Glasses for Their Evaluation as Transparent Large Band Gap Semiconductors., Journal of Alloys and Compounds, 748 (2018) 687–93 Elsevier.
[14] Saad, Mohammed, and Marcel Poulain. ,Glass Forming Ability Criterion., Materials Science Forum, vol. 19, Trans Tech Publ, 1987, pp. 11–18.
[15] Novatski, A., et al. ,Thermal and Optical Properties of Lithium-Zinc-Tellurite Glasses., Materials Chemistry and Physics, 231 (2019) 150–58 Elsevier.
[16] Elkhoshkhany, N., et al. ,Effect of Heat Treatment on Erbium-Doped Tellurite Glass., Materials Chemistry and Physics, 221 (2019) 467–76 Elsevier.
[17] Upender, G., Vasant G. Sathe, et al. ,Raman Spectroscopic Characterization of Tellurite Glasses Containing Heavy Metal Oxides., Physica B: Condensed Matter, 405(5) (2010) 1269–73 Elsevier.
[18] Sayyed, M. I., and G. Lakshminarayana. ,Structural, Thermal, Optical Features and Shielding Parameters Investigations of Optical Glasses for Gamma Radiation Shielding and Defense Applications., Journal of Non-Crystalline Solids, 487 (2018) 53–59 Elsevier.
[19] Komatsu, Teruhisa, et al. ,Temperature and Light Responses of Alga Caulerpa Taxifolia Introduced into the Mediterranean Sea., Marine Ecology Progress Series, 146 (1997) 145–53.
[20] Lyon, L. Andrew, et al. ,Raman Spectroscopy., Analytical Chemistry, 70(12) (1998) 341–62 American Chemical Society.
[21] z Guimbretière, Guillaume, et al. ,Combined Vibrational Multipolar Analyses and Ab Initio Cluster Description of Glasses: Toward Structural Insights in Vitreous v-P2O5., Vibrational Spectroscopy, 63 (2012) 426–31 Elsevier.
[22] Price, P. B., et al. ,Search for Highly Ionizing Particles at the Fermilab Proton-Antiproton Collider., Physical Review Letters, 59(22) (1987) 2523 APS.
[23] Ivascu, C., et al. ,Spectroscopic Investigation of P2O5–CdO–Li2O Glass System., Journal of Non-Crystalline Solids, 359 (2013) 60–64 Elsevier.
[24] Santos, Luı́s F., et al. ,Raman Spectra and Structure of Fluoroaluminophosphate Glasses., Journal of Non-Crystalline Solids, vol. 284(1–3) (2001) 43–48 Elsevier.
[25] Oliveira, CIRD, and LFCD Oliveira. ,FAD Filho, Y. Messaddeq and SJL Ribeiro., Spectrochim. Acta, Part A, 61(2005) 2023.
[26] Sastry, S. Sreehari, and B. Rupa Venkateswara Rao. ,Spectroscopic Studies of Copper Doped Alkaline Earth Lead Zinc Phosphate Glasses., Physica B: Condensed Matter, 434 (2014) 159–64 Elsevier.
[27] Paz, E. C., et al. ,Physical, Thermal and Structural Properties of Calcium Borotellurite Glass System., Materials Chemistry and Physics, 178 (2016) 133–38 Elsevier.
[28] Pawar, Pravina P., and Govind K. Bichile. ,Studies on Mass Attenuation Coefficient, Effective Atomic Number and Electron Density of Some Amino Acids in the Energy Range 0.122–1.330 MeV., Radiation Physics and Chemistry, 92 (2013) 22–27 Elsevier.
[29] Padmaja, G., and P. Kistaiah. ,Infrared and Raman Spectroscopic Studies on Alkali Borate Glasses: Evidence of Mixed Alkali Effect., The Journal of Physical Chemistry A, 113(11) (2009) 2397–404 ACS Publications.
[30] Upender, G., Vasant G. Sathe, et al. ,Raman Spectroscopic Characterization of Tellurite Glasses Containing Heavy Metal Oxides., Physica B: Condensed Matter, 405(5) (2010) 1269–73 Elsevier.
[31] Ingram, Malcolm D. ,Ionic Conductivity in Glass., Physics and Chemistry of Glasses, 28(6) (1987) 215–34.
[32] Gaafar, M. S., et al. ,Ultrasonic Studies on Alkali Borate Tungstate Glasses., Journal of Physics and Chemistry of Solids, 70(1) (2009) 173–79 Elsevier.