To Study the Structural Characterization of the Polyaniline/CoFe2O4 Nanocomposites

International Journal of Applied Physics

© 2022 by SSRG - IJAP Journal

Volume 9 Issue 2

Year of Publication : 2022

Authors : Seema , Sunil Rohilla , Sonia Arora , Saneh Lata , Anita Yadav , Preeti kaushik

10.14445/23500301/IJAP-V9I2P101

How to Cite?

Seema , Sunil Rohilla , Sonia Arora , Saneh Lata , Anita Yadav , Preeti kaushik, "To Study the Structural Characterization of the Polyaniline/CoFe2O4 Nanocomposites," SSRG International Journal of Applied Physics, vol. 9,  no. 2, pp. 1-6, 2022. Crossref, https://doi.org/10.14445/23500301/IJAP-V9I2P101

Abstract:

In the present research work, Polyaniline/CoFe2O4 nanocomposites were prepared using the co-precipitation method, which is economical and eco-friendly. The CoFe2O4 nanoparticles get adhered into a polymer using the in-situ chemical polymerization method. The various techniques were approached to characterize the prepared sample, such as XRD and FTIR. The peaks obtained at around 20.3 degrees and 25.2 degrees show the amorphous nature of PANI (low crystallinity). The appearance of characteristic diffraction peaks achieved at 35.5 degrees and 43.2 degrees ascribed to wellarranged crystalline cobalt ferrite pointing to the successive synthesis by co-precipitation route. Different analyses such as Debye- Scherrer, Halder, Wagner (H-W), and Williamson Hall (W-H) methods have investigated various parameters such as crystallite size and strain. The achieved values of crystallite size were highly correlated with Debye- Scherrer, Halder Wagner (H-W), and Williamson Hall (W-H) plots. The FTIR characterization confirmed the bonding among the Polyaniline/CoFe2O4 nanocomposites, which gets well-matched with XRD results.

Keywords:

Debye-Scherrer, Halder Wagner, PANI, Strain, W-H plots.

References:

[1] M. Kooti, A. Naghdisedeh, Kh. Gheisari, A. Figuerola. Synthesis, characterization, and performance of nanocomposites containing reduced graphene oxide, polyaniline, and cobalt ferrite, Physica B: Condensed Matter (612) (2021) 412974. DOI: https://doi.org/10.1016/j.physb.2021.412974
[2] Tian Chen, Bo Liu. Dielectric properties of graphene quantum dot-cobalt ferrite-poly (vinylidene fluoride) ternary composites. Materials Letters 209 (2017) 163-166. DOI: https://doi.org/10.1016/j.matlet.2017.07.088
[3] Ming Qin, Qin Shuaia, Guanglei Wu, Bohan Zheng, Zhengdong Wang, Hongjing Wub. Zinc ferrite composite material with controllable morphology and its Applications.Materials science and engineering B 224 (2017) 125-138. DOI: https://doi.org/10.1016/j.mseb.2017.07.016
[4] Yuandong Penga, Yi Yi, Liya Li, Hengyu Ai, Xiaoxu Wang, Lulu Chen. Fe-based soft magnetic composites coated with NiZn ferrite are prepared by a co-precipitation method. Journal of Magnetism and Magnetic Materials 428 (2017) 148-153. DOI:[ https://doi.org/10.1016/j.jmmm.2016.12.024]
[5] Victor Y. Zenou, Snejana Bakardjieva. Microstructural analysis of undoped and moderately Sc-doped TiO2 anatase nanoparticles using Scherrer equation and Debye function analysis. Materials Characterization 144 (2018) 287-296. DOI:https://doi.org/10.1016/j.matchar.2018.07.022
[6] Debojyoti Nath, Fouran Singh, Ratan Das. X-ray diffraction analysis by Williamson- Hall, Halder-Wagner, and size-strain plot methods of CdSe nanoparticles-a comparative study. Materials Chemistry and Physics 239 (2020)12-21. DOI: https://doi.org/10.1016/j.matchemphys.2019.122021
[7] M.A. Gabal, A.A. Al-Juaid, S. El-Rashed, M.A. Hussein, Y.M. Al Angari. Polyaniline/Co0.6Zn0.4Fe2O4 core-shell nanocomposites. Synthesis, characterization, and properties. Journal of Alloys and Compounds 747 (2018) 83-90. DOI: https://doi.org/10.1016/j.materresbull.2010.06.021
[8] Rajesh Sharma, Anita Yadav, Sonia Arora, Nawal Kishore. To study the structural properties of cobalt doped tin oxide nanostructured by using Williamson-Hall and size-strain plot methodology. Materials today: PROCEEDINGS 44 (2021) 4651-4656 DOI: https://doi.org/10.1016/j.matpr.2020.10.927
[9] Munmun Basak, Md. Lutfor Rahman, Md. Farid Ahmed, Bristy Biswas, Nahid Sharmin. X-ray diffraction peak profile analysis to determine the structural parameters of cobalt ferrite nanoparticles using Debye –Scherrer, Williamson- Hall, Halder – Wagner, and SizeStrain plot: Different precipitating agent approach. Journal of Alloys and Compounds 895 (2022) 162694. DOI:https://doi.org/10.1016/j.jallcom.2021.162694
[10] Hongbo Gu, Hongyuan Zhang, Jing Lin, Qian Shao, David P. Young, Luyi Sun, T.D. Shen, Zhanhu Guo, Large negative giant magnetoresistance at room temperature and electrical transport in cobalt ferrite-polyaniline nanocomposites.Polymer 143 (2018) 324- 330.
[11] kasala suresha, thermoelectric power in wide bandgap semiconductor ZnO nanowire, SSRG International Journal of Applied Physics, 9(1) (2022) 9-11. https://doi.org/10.14445/23500301/IJAP-V9I1P102
[12] Firoz Ahmed, Md. Ibrahim, H. Mondal, Md. Nazmul Huda, Md. Khademul Islam, Nano ZnO Loaded Trimethyl Chitosan Chloride- A promising Bio-composite for Antimicrobial and wound Healing Fabric. SSRG International Journal of Applied Physics, 9(1) (2022) 6- 10 https://doi.org/10.14445/23942592/IJPTE-V9I1P102
[13] K. vimala,Y.M. Mohan, K. Varaprasad,N.N. Redd,S. Ravindra, NS. Naidu, Fabrication of curcumin Encapsulated Chit osan PVA Silver nanocomposite films for improved Antimicrobial activity, Journal of Biomaterials and Nanobiotechnology. 2(2011) 55-64.
[14] R.Laur, D.Goyal, S.Agnihotri, Chitosan/PVA silver nanocomposite for Butachlor Removal: Fabrication, characterization, adsorption Mechanism and isotherms, carbohydrate polymers.262 (2021) 117906.
[15] M.K. Hassan, A. Abukmail, A.J. Hassiba, K.A. Mauritz,A. Elzatahry, PVA/Chitosan/Silver nanoparticles electrospun nanocomposites: Molecular relaxations investigated by modern broadband Dielectric Spectroscopy, Nanomaterials.8(11)(2018) 888.
[16] R.Rajendran, C. Balakumar,H.A.M. Ahamed, S. Jayakumar, k. Vaideki, E.M. Rajesh, Use of zinc oxide nanoparticles for production of antimicrobial textiles, International Journal of Engineering, Science and Technology.2(1) (2010) 202-208.
[17] B. jeevanantham, Youngseoksong, Heemanchoe, M.K. Shobana, Structural and optical characteristics of cobalt ferrite nanoparticles, Materials Letters:X 12(2021) 100-105, https://doi.org/10.1016/j.mlblux.2021.100105
[18] Deepali, D. Andhare, Supriya, R. patade, Jitendra S. Kounsalye, K.M. Jadhav.Effect of Zn doping on structural, magnetic, and optical properties of cobalt ferrite nanoparticles synthesized via. Co-precipitation method. Physica B: Condensed Matter 583(2020) 412051. https://doi.org/10.1016/j.physb.2020.412051
[19] Bikramjit Kaur,Ruchika Tanwar, Uttam K. Mandal. Effect of calcination and surface Functionalization of nanoparticles on structural, magnetic, and electrical properties of polyaniline Ni.5Zn.5Fe2O4 nanocomposites. Colloida and surfaces A: physicochemical and Engineering Aspects.628 (2021) 127273. https://doi.org/10.1016/j.colsurfa.2021.127273
[20] M. M. Bagheri, M. Valid, A. Gholipour, P. Makvandi, E. Sharifi, Chitosan Nanofiber Biocomposites for Potential Wound Healing Applications: Antioxidant Activity with Synergic Anti-Bacterial Anti-Bacterial Effect, Bioengineering & Translational Medicine. 7(1) (2022) 10254
[21] P.S.V.Shanmukhi, Dr.K.Chandramouli and Dr.P.V.S.Machiraju, (2016) Investigative Study of Structural morphology of Polypropylene and BaCo3 – Nanoparticle Composites. SSRG International Journal of Material Science and Engineering 2(3), 8 - 12.
[22] Seema Sharma, Sunil Rohilla, Synthesis of nanocomposites of NiFe2O4/SiO2 through co-precipitation method and structural characterization using Rietveld refinement, AIP Conference Proceedings 2270, (2020) 110023 https://doi.org/10.1063/5.0020045.
[23] Haibo Yang, Ting Ye, Ying Lin, Jianfeng Zhu, Fen Wang, Microwave absorbing properties of the ferrite composites based on graphene. Journal of Alloys and Compounds 683 (2016) 567-574.
[24] Moonis Ali Khan, Mohammad Mezbaul Alam, Mu Naushad, Zeid Abdullah Alothman, Mahendra Kumar, Tansir Ahamad Solgel assisted synthesis of porous nano-crystalline CoFe2O4 composite and its application in the removal of brilliant blue -R from aqueous phase: An eco-friendly and economical approach. Chemical Engineering Journal 279 (2015) 416–424.
[25] Duan Wang, Jingli Wu, Daxun Bai, Rongrong Wang, Feng Yao, Sailong Xu, Mesoporous spinel ferrite composite derived from a ternary MgZnFe-layered double hydroxide precursor for lithium storage. Journal of Alloys and Compounds 726 (2017) 306- 314. DOI: https://doi.org/10.1016/j.polymer.2018.04.008
[26] R. Nawalakhe, Q. Shi, N. Vitchuli, J. Noar, J.M. Caldwell, F. Breidt, M.A. Bourham, X. Zhang, M.G. McCord, Novel Atmospheric Plasma Enhanced Chitosan Nanofiber/Gauze Composite Wound Dressings, Journal of Applied Polymer Science. 129(2) (2013) 916- 923.