Effect of Various Parameters on the Strength of Flyash and GGBS Geopolymer Mortar
International Journal of Civil Engineering |
© 2024 by SSRG - IJCE Journal |
Volume 11 Issue 9 |
Year of Publication : 2024 |
Authors : I.V. Ranga Ramanujam, K. Ramachandra Reddy, N.V. Ramana |
How to Cite?
I.V. Ranga Ramanujam, K. Ramachandra Reddy, N.V. Ramana, "Effect of Various Parameters on the Strength of Flyash and GGBS Geopolymer Mortar," SSRG International Journal of Civil Engineering, vol. 11, no. 9, pp. 12-26, 2024. Crossref, https://doi.org/10.14445/23488352/IJCE-V11I9P102
Abstract:
Geopolymers are a special class of inorganic polymers that are now promising binders developed by the activation of solid-state alumina-silicate with alkaline solution. Due to their environmental sustainability, geopolymers have been shown to be effective substitutes for cement binders in recent times. Additionally, its performance in an aggressive environment is encouraging, and these binders are gradually replacing cement concrete as a preferred option in aggressive situations. Numerous binders, including flyash, GGBS, metakaolin, and Palm Oil Flyash (POFA), have been the subject of extensive research, either alone or in combination with one or both binders. The current study's goal is to ascertain how different Liquid-to-Binder ratios (LB Ratio), NaOH molarities (M), and sodium silicate-to-sodium hydroxide ratios (alkaline solution ratio) affect the compressive strength of geopolymer mortar based on flyash and GGBS. The molarities of NaOH used in the study are 10 M, 12 M, 14 M, and 16 M. The investigations are carried out by altering the liquid binder ratio of 0.4 and 0.45. The ratios of sodium hydroxide to sodium silicate are 1.5, 2.0, and 2.5. A total of twenty-four experimental mixes of flyash and GGBS are made for each geopolymer mortar. The qualities of the fresh mortar are ascertained, together with the compressive strengths. The effect of various molar ratios on the compressive strength of flyash and GGBS mortar is studied. From the above studies, the geopolymer mortar with GGBS has shown improved results compared to the geopolymer mortar with flyash. Among all the mixes the mix with 14M exhibited superior performance in compressive strength. The specimens with an LB ratio of 0.45, AL ratio of 2.0 and 14M yielded a maximum strength of 52.69 MPa.
Keywords:
Molarity, Flyash, GGBS, Setting time, Sodium hydroxide molarity.
References:
[1] B.W. Jo, S.K. Park, and M.S. Park, “Strength and Hardening Characteristics of Activated Fly Ash Mortars,” Magazine of Concrete Research, vol. 59, no. 2, pp. 121-129, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Sanjay kumar, Rakesh Kumar, and S.P. Mehrotra, “Influence of Granulated Blast Furnace Slag on the Reaction, Structure and Properties of Fly Ash Based Geopolymer,” Journal of Materials Science, vol. 45, pp. 607-615, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Ashley Russell Kotwal et al., “Characterization and Early Age Physical Properties of Ambient Cured Geopolymer Mortar Based on Class C Fly Ash,” International Journal of Concrete Structures and Materials, vol. 9, pp. 35-43, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Hong Lich Dinh et al., “Influence of Si/Al Molar Ratio and Ca Content on the Performance of Fly Ash-Based Geopolymer Incorporating Waste Glass and GGBFS,” Construction and Building Materials, vol. 411, pp. 1-16, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Marios Soutsos et al., “Factors Influencing the Compressive Strength of Fly Ash Based Geopolymers,” Construction and Building Materials, vol. 110, pp. 355-368, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[6] M. Talha Junaid et al., “A Mix Design Procedure for Low Calcium Alkali Activated Fly Ash-Based Concretes,” Construction and Building Materials, vol. 79, pp. 301-310, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Subhash V. Patankar, Sanjay S. Jarnkar, and Yuvraj M. Ghuga, “Effect of Sodium Hydroxide on Flow and Strength of Fly Ash Based Geopolymer Mortar,” Journal of Structural Engineering, vol. 39, no. 1, pp. 7-12, 2012.
[Google Scholar]
[8] Pradip Nath, and Prabir Kumar Sarker, “Effect of GGBFS on Setting, Workability and Early Strength Properties of Fly Ash Geopolymer Concrete Cured in Ambient Condition,” Construction and Building Materials, vol. 66, pp. 163-171, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Subhashree Samantasinghar, and Suresh Prasad Singh, “Fresh and Hardened Properties of Fly Ash–Slag Blended Geopolymer Paste and Mortar,” International Journal of Concrete Structures and Materials, vol. 13, pp. 1-12, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Ahmer Ali Siyal et al., “Effects of Parameters on the Setting Time of Fly Ash Based Geopolymers Using Taguchi Method,” Procedia Engineering, vol. 148, pp. 302-307, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Ali Allahverdi, and Mostafa Vafaei, “Durability of Geopolymer Mortar Based on Waste-Glass Powder and Calcium Aluminate Cement in Acid Solutions,” Journal of Materials in Civil Engineering, vol. 29, no. 10, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[12] N.K. Lee, and H.K. Lee, “Setting and Mechanical Properties of Alkali-Activated Fly Ash/Slag Concrete Manufactured at Room Temperature,” Construction and Building Materials, vol. 47, pp. 1201-1209, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Eslam Gomaa et al., “Fresh Properties and Early Compressive Strength of Alkali-Activated High Calcium Fly Ash Paste,” Proceedings of the 4th International Geotechnical Congress - Works - Structures, pp. 497-507, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[14] Azizul Islam et al., “The Development of Compressive Strength of Ground Granulated Blast Furnace Slag-Palm Oil Fuel Ash-Fly Ash Based Geopolymer Mortar,” Materials and Design, vol. 56, pp. 833-841, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[15] P. Ganapati Naidu et al., “A Study on Strength Properties of Geopolymer Concrete with Addition of G.G.B.S,” International Journal of Engineering Research and Development, vol. 2, no. 4, pp. 19-28, 2012.
[Google Scholar] [Publisher Link]
[16] Amir Fauzi et al., “Effect of Alkaline Solution to Fly Ash Ratio on Geopolymer Mortar Properties,” Key Engineering Materials, vol. 733, pp. 85-88, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Zongjin Li, and Sifeng Liu, “Influence of Slag as Additive on Compressive Strength of Fly Ash-Based Geopolymer,” Journal of Materials in Civil Engineering, vol. 19, no. 6, pp. 470-474, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[18] K. Sankar, and D. Shoba Rajkumar, “Experimental Investigation on Geopolymer Mortar Using Fly Ash and GGBS,” Veterinary Practice, vol. 40, pp. 572-584, 2020.
[Google Scholar]
[19] Subhash V. Patankar, Yuwaraj M. Ghugal, and Sanjay S. Jamkar, “Effect of Concentration of Sodium Hydroxide and Degree of Heat Curing on Fly Ash-Based Geopolymer Mortar,” Indian Journal of Materials Science, vol. 2014, no. 1, pp. 1-6, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[20] Gokhan Gorhan, and Gokhan Kurklu, “The Influence of the NaOH Solution on the Properties of the Fly Ash-Based Geopolymer Mortar Cured at Different Temperatures,” Composites Part B: Engineering, vol. 58, pp. 371-377, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[21] G.S. Manjunath et al., “Compressive Strength Development in Ambient Cured Geo-Polymer Mortar,” International Journal of Earth Sciences and Engineering, vol. 4, no. 6, pp. 830-834, 2011.
[Google Scholar]
[22] Radomir Zejak et al., “Mechanical and Microstructural Properties of the Fly-Ash-Based Geopolymer Paste and Mortar,” Materials and Technologies, vol. 47, no. 4, pp. 535-540, 2013.
[Google Scholar] [Publisher Link]
[23] D. Hardjito, and B.V. Rangan, Development and Properties of Low-Calcium Fly Ash-Based Geopolymer Concrete, Research Report GC, 2005. [Online]. Available: https://www.geopolymer.org/library/technical-papers/17-development-and-properties-of-low-calcium-fly-ash-based-geopolymer-concrete/
[24] Mohd Mustafa Al Bakri Abdullah et al., “The Relationship of NaOH molarity, Na2SiO3/NaOH Ratio, Fly Ash /Alkaline Activator Ratio, and Curing Temperature to the Strength of Fly Ash Based Geopolymer,” Advanced Materials Research, vol. 328-330, pp. 1475-1482, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Muhammad Nasir et al., “Effect of Alkaline Activators on the Fresh Properties and Strength of Silico-Manganese Fume-Slag Activated Mortar,” Advances in Concrete Construction, vol. 10, no. 5, pp. 403-416, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[26] Ali Rafeet et al., “Guidelines for Mix Proportioning of Fly Ash/GGBS Based Alkali Activated Concretes,” Construction and Building Materials, vol. 147, pp. 130-142, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[27] M.S. Morsy et al., “Effect of Sodium Silicate to Sodium Hydroxide Ratios on Strength and Microstructure of Fly Ash Geopolymer Binder,” Arabian Journal for Science and Engineering, vol. 39, no. 6, pp. 4333-4339, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[28] Ubolluk Rattanasak, and Prinya Chindaprasirt, “Influence of NaOH Solution on the Synthesis of Fly Ash Geopolymer,” Minerals Engineering, vol. 22, no. 12, pp. 1073-1078, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[29] Apha Sathonsaowaphak, Prinya Chindaprasirt, and Kedsarin Pimraksa, “Workability and Strength of Lignite Bottom Ash Geopolymer Mortar,” Journal of Hazardous Materials, vol. 168, no. 1, pp. 44-50, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[30] Guohao Fang et al., “Workability and Mechanical Properties of Alkali-Activated Fly Ash-Slag Concrete Cured at Ambient Temperature,” Construction and Building Materials, vol. 172, pp. 476-487, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[31] P. Chindaprasirt, T. Chareerat, and V. Sirivivatnanon, “Workability and Strength of Coarse High Calcium Fly Ash Geopolymer,” Cement and Concrete Composites, vol. 29, no. 3, pp. 224-229, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[32] Zarina Yahya et al., “Effect of Solids-to-Liquids, Na2SiO3-to-NaOH and Curing Temperature on the Palm Oil Boiler Ash (Si+Ca) Geopolymerisation System,” Materials, vol. 8, no. 5, pp. 2227-2242, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[33] Mohammed Ibrahim et al., “Effect of Alkaline Activators and Binder Content on the Properties of Natural Pozzolan-Based Alkali Activated Concrete,” Construction and Building Materials, vol. 147, pp. 648-660, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[34] Ehsan Mohseni, “Assessment of Na2SiO3 to NaOH Ratio Impact on the Performance of Polypropylene Fiber-Reinforced Geopolymer Composites,” Construction and Building Materials, vol. 186, pp. 904-911, 2018.
[CrossRef] [Google Scholar] [Publisher Link]