Fabrication and Characterization of Perovskite Solar Cell with Fluorine Doped Electron Transport Layer

International Journal of Electrical and Electronics Engineering
© 2024 by SSRG - IJEEE Journal
Volume 11 Issue 6
Year of Publication : 2024
Authors : Sweta, Laxmikant Prasad Purohit, Nitin Kumar Sharma, Hitender Kumar Malik, Vinod Kumar
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How to Cite?

Sweta, Laxmikant Prasad Purohit, Nitin Kumar Sharma, Hitender Kumar Malik, Vinod Kumar, "Fabrication and Characterization of Perovskite Solar Cell with Fluorine Doped Electron Transport Layer," SSRG International Journal of Electrical and Electronics Engineering, vol. 11,  no. 6, pp. 259-266, 2024. Crossref, https://doi.org/10.14445/23488379/IJEEE-V11I6P128

Abstract:

In today's world, the utilization of clean energy has become imperative, to meet this demand, humanity has long tapped into inexhaustible energy resources. Among these, harnessing energy from solar radiation through solar cells stands out as a prominent example.  Regarding solar energy, Perovskite Solar Cells (PSCs) devices have been a revolution in this field. The reason behind their popularity is their performance. In just ten years, their performance efficiency increased at a quick pace. In comparison to traditional silicon-based Solar Cells (SC), PSCs have higher tunability and lower fabrication costs. PSCs can be constructed using either n-i-p or p-i-n configurations. Here, 'n' stands for  ‘Electron Transport Layer (ETL)’, 'p' stands for ‘Hole Transport Layer (HTL)’, and 'i' shows the active material layer, which is positioned between the ETL and HTL. In the current study, TiO2 is employed as the ETL, NiO serves as the HTL, and perovskite is utilized as the active layer. Here, titanium tetra isopropoxide precursor solution serves the purpose in the investigation for developing films of unadulterated TiO2 and F - TiO2 using the sol-gel followed by a spin coating process, different concentrations of F-doped TiO2. The produced film is characterized using a range of techniques, including XRD and SEM, to ascertain its structural properties and surface morphology. The electrical properties were evaluated to determine the current density and voltage using a solar simulator, which subsequently facilitated the calculation of device performance. XRD analysis confirmed the crystalline nature and particle size. Scanning Electron Microscopy SEM images revealed distinct layers, clearly indicating proper deposition of all layers. Electrical measurements demonstrated that the concentration of fluorine doping significantly affects the performance of the device. The PCE (Power Conversion Efficiency) of the fluorine-doped samples is much more impressive than that of the unadulterated samples in the context of the obtained results.

Keywords:

Sol-gel, AC conductivity, Power conversion efficiency, Perovskite Solar Cell, Renewable energy.

References:

[1] Pabitra K. Nayak et al., “Photovoltaic Solar Cell Technologies: Analysing the State of the Art,” Nature Reviews Materials, vol. 4, no. 4, pp. 269-285, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Ehsanul Kabir et al., “Solar Energy: Potential and Future Prospects,” Renewable and Sustainable Energy Reviews,” vol. 82, pp. 894-900, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Nathan S. Lewis, and Daniel G. Nocera, “Powering the Planet: Chemical Challenges in Solar Energy Utilization,” PNAS, vol. 103, no. 43, pp. 15729-15735, 2006.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Priyanka Roy et al., “Perovskite Solar Cells: A Review of the Recent Advances,” Coatings, vol. 12, no. 8, pp. 1-24, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Jian Wu et al., “Fabrication of Efficient Organic-Inorganic Perovskite Solar Cells in in Ambient Air,” Nanoscale Research Letters, vol. 13, pp. 1-7, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Di Liu et al., “Tailoring Morphology and Thickness of Perovskite Layer for Flexible Perovskite Solar Cells on Plastics: The Role of CH3NH3I Concentration,” Solar Energy, vol. 147, pp. 222-227, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Ningxia Gu et al., “Fabrication of Efficient and Stable Perovskite Solar Cells in Open Air through Adopting a Dye Interlayer,” Sustainable Energy & Fuels, vol. 6, no. 18, pp. 4275-4284, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Hyun Suk Jung, and Nam-Gyu Park, “Perovskite Solar Cells: From Materials to Devices,” Small, vol. 11, no. 1, pp. 10-25, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Enbing Bi et al., “Diffusion Engineering of Ions and Charge Carriers for Stable Efficient Perovskite Solar Cells,” Nature Communications, vol. 8, pp. 1-7, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Y. Kumar et al., “Effect of Heat Treatment on the Electrical Properties of Perovskite Solar Cells,” Solar Energy Materials and Solar Cells, vol. 157, pp. 10-17, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Gwang Su Shin et al., “Rapid Crystallization in Ambient Air for Planar Heterojunction Perovskite Solar Cells,” Electronic Materials Letters, vol. 13, pp. 72-76, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Weijie Chen et al., “A Semitransparent Inorganic Perovskite Film for Overcoming Ultraviolet Light Instability of Organic Solar Cells and Achieving 14.03% Efficiency,” Advanced Materials, vol. 30, no. 21, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Qidong Tai et al., “Efficient and Stable Perovskite Solar Cells Prepared in Ambient Air Irrespective of the Humidity,” Nature Communications, vol. 7, pp. 1-8, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[14] Paul Rappaport, “The Photovoltaic Effect and Its Utilization,” Solar Energy, vol. 3, no. 4, pp. 8-18, 1959.
[CrossRef] [Google Scholar] [Publisher Link]
[15] N.D. Kaushika, Anuradha Mishra, and Anil K. Rai, Solar Photovoltaics - Technology, System Design, Reliability and Viability, 1st ed., Springer Cham, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Ajay Sharma, R.K. Karn, and S.K. Pandiyan, “Synthesis of TiO2 Nanoparticles by Sol-Gel Method and their Characterization,” Journal of Basic and Applied Engineering Research, vol. 1, no. 9, pp. 1-5, 2014.
[Google Scholar] [Publisher Link]
[17] Abraha Tadese Gidey et al., “First Conventional Solution Sol-Gel-Prepared Nanoporous Materials of Nickel Oxide for Efficiency Enhancing and Stability Extending MAPbI3 Inverted Perovskite Solar Cells,” ACS Applied Energy Materials, vol. 4, no. 7, pp. 6486-6499, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[18] K. Anandan, and V. Rajendran, “Morphological and Size Effects of NiO Nanoparticles via Solvothermal Process and their Optical Properties,” Materials Science in Semiconductor Processing, vol. 14, no. 1, pp. 43-47, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Diego Di Girolamo et al., “Progress, Highlights and Perspectives on NiO in Perovskite Photovoltaics,” Chemical Science, vol. 11, no. 30, pp. 7746-7759, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[20] Wenjuan Li et al., “Generation of Oxygen Vacancies in Visible Light Activated One-Dimensional Iodine TiO2 Photocatalysts,” RSC Advances, vol. 4, no. 70, pp. 36959-36966, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[21] Anand Kumar Tripathi et al., “Structural, Optical and Photoconductivity of Sn and Mn Doped TiO2 Nanoparticles,” Journal of Alloys and Compounds, vol. 622, pp. 37-47, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[22] Sakhamudi Sai Narender et al., “Nickel Oxide Nanoparticles: A Brief Review of their Synthesis, Characterization, and Applications,” Chemical Engineering & Technology, vol. 45, no. 3, pp. 397-409, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[23] Shuangyong Sun et al., “The Origin of High Efficiency in Low-Temperature Solution-Processable Bilayer Organometal Halide Hybrid Solar Cells,” Energy & Environmental Science, vol. 7, no. 1, pp. 399-407, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Dianyi Liu, Jinli Yang, and Timothy L. Kelly, “Compact Layer Free Perovskite Solar Cells with 13.5% Efficiency,” Journal of the American Chemical Society, vol. 136, no. 49, pp. 17116-17122, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Cuiping Zhang et al., “A Review on Organic Hole Transport Materials for Perovskite Solar Cells: Structure, Composition and Reliability,” Materials Today, vol. 67, pp. 518-547, 2023.
[CrossRef] [Google Scholar] [Publisher Link]