Trace and REEs Geochemistry, A Tool To Study Mudrocks And Quaternary Deposits Found In Babouri-Figuil Intracontinental Basin (North Cameroon): Provenance, Depositional Conditions, And Paleoclimate
International Journal of Geoinformatics and Geological Science |
© 2021 by SSRG - IJGGS Journal |
Volume 8 Issue 2 |
Year of Publication : 2021 |
Authors : Nguo Sylvestre Kanouo, Aubin Nzeugang Nzeukou, Arnaud Patrice Kouské, Clarisse Tcheombé Bahané, Robert Kringle, Emmanuel Archelaus Afanga Basua, Nathalie Fagel |
How to Cite?
Nguo Sylvestre Kanouo, Aubin Nzeugang Nzeukou, Arnaud Patrice Kouské, Clarisse Tcheombé Bahané, Robert Kringle, Emmanuel Archelaus Afanga Basua, Nathalie Fagel, "Trace and REEs Geochemistry, A Tool To Study Mudrocks And Quaternary Deposits Found In Babouri-Figuil Intracontinental Basin (North Cameroon): Provenance, Depositional Conditions, And Paleoclimate," SSRG International Journal of Geoinformatics and Geological Science, vol. 8, no. 2, pp. Provenance, Depositional Conditions, And Paleoclimate" SSRG International Journal of Geoinformatics and Geological Science 82 (202167-88, 2021. Crossref, https://doi.org/10.14445/23939206/IJGGS-V8I2P107
Abstract:
Trace and REEs geochemical analysis was carried out on mudrocks and fine-grained-rich Quaternary deposits from five pits dug. Results were used to chararacterize each sedimentatry formation and to determine the provenance, tectonic setting, depositional conditions, and paleoclimate. Mudrocks show relatively high Sr, Ba, Zr, and LREE contents with Sr being exceptionally high in schistose marls, which generally have the lowest Ba and Zr contents. Provenance interpretation suggests that the lithified sediments (all from Upper continental Crust) were sourced mainly from post-Archean strata. La/Th versus Hf, Co/Th versus La/Sc, and La/Yb versus ΣREE binary diagrams show continental tholeiitic basaltic, alkaline basaltic, and/or sedimentary rocks sources, with part of the later being carbonaceous. Depositional interpretations suggest that these studied lithified sediments were mainly deposited in a passive continental margin setting under oxidizing to reducing conditions. Paleoclimatic and paleosalinity analyses suggest that the climatic conditions in Babouri-Figuil during depositional periods were warm and humid, cool and arid, and warm and arid. Mudstone’s and schistose marl’s sediments were mainly deposited in lacustrine and marine environments, respectively.Quaternary deposits characterizations show that those from Pomla and Sorawel have relatively higher trace and REEs than those from Délélé, Kolé, and Mayo Figuil. Provenance studies suggest that the sediments were mainly originated from Upper Continental Crust, and post-Archean strata. Sediments in Délélé and Kolé were sourced from felsic, mafic, and sedimentary rocks. Those in Pomla, Sorawel, and Mayo Figuil were mainly originated from felsic rocks. Depositional interpretation, suggest that the studied sediments were deposited in a range from reducing to oxidizing conditions. Paleoclimatic interpretations suggest that Babouri-Figuil was arid and cool during deposition in Pomla and arid and warm during deposition in Délélé, Sorawel, Kole, and Mayo Figuil.
Keywords:
Cameroon, Babouri-Figuil Basin, mudrocks, Quatenary deposits, trace and REEs, provenance, tectonic setting, deposition, paleoclimate.
References:
[1] Fang X, Peng B, Zhang K, Zeng D, Kuang X, Wu B, Tu X, Zhaoliang Song Z, Xiao Y, Yang Z, Xie W, Bao Z, Tan C, Wan D., Geochemistry of major and trace elements in sediments from inlets of the Xiangjiang and Yuanjiang River to Dongting Lake, China. Env. Earth Sci. https://doi.org/10.1007/s12665-017-7193-5., (2018).
[2] Xie G, Shen Y, Liu S, Hao W x., Trace and rare earth element (REE) characteristics of mudstones from Eocene pinghu formation and Oligocene huagang formation in XihuSag, east China sea basin: implications for provenance, depositional conditions and paleoclimate. Mar. Petrol. Geol. 1, 1-35.
[3] Balaram V., Rare earth elements: A review of applications, occurrence, exploration, analysis, recycling, and environmental impact. Geosci. Front. 10 (2019) 1285-1303.
[4] Kamgang P, Chazot G, Njonfang E, Ngongang NBT, Tchoua FM., Mantle sources and magma evolution beneath the Cameroon volcanic line: Geochemistry of mafic rocks from the Bamenda Mountains (NW Cameroon). Gondwana Res. 24 (2013) 727-741.
[5] Kanouo SN, Yongue FR, Ghogomu RT, Kouske PA, Njonfang E, Yomeun BS, Basua AAE Petro-geochemistry, genesis and economic aspects of mafic volcanic rocks in the west and southern part of the Mamfe Basin (SW Cameroon, Central Africa). J. Geol. Geophy. DOI: 10.4172/2381-8719.1000298., (2017).
[6] Kanouo SN, Wang L, Kouske PA, Yomeun BS, Basua AAE., Petro-geochemistry, genesis and economic aspect of syenitic and mafic rocks in Mind if Complex, Far North Cameroon, Central Africa. Int. J. Geosci. 10 (2019) 1081-1114.
[7] Ominigbo OE, Ukwang EE, Okumoko DP, Ukpai UJ ., Petrogenesis and Tectonic Setting of the Basement Rocks around Irruan Area, Bamenda Massif, SE Nigeria. J. Geosci. Geom. 8(1) (2020) 35-44. [8] Aliyari F, Rastad E, Goldfarb JR, Sharif AJ., Geochemistry of hydrothermal alteration at the Qolqoleh gold deposit, northern Sanandaj-Sirjan metamorphic belt, northwestern Iran: Vectors to high-grade ore bodies. J. Geochem. Expl. 140 (2014) 111-125.
[9] Hu H, Li WJ, Harlov ED, Lentz RD, McFarlane MRC, Yang HY ., A genetic link between iron oxide-apatite and iron skarn mineralization in the Jinniu volcanic basin, Daye district, eastern China: Evidence from magnetite geochemistry and multi-mineral U-Pb geochronology. Geol. Soc. Am. https://doi.org/10.1130/B35180.1., (2019).
[10] Kravtsova GR, Tauson LV, Goryachev AN, Makshakov SA, Yu K, Arsent EV, Lipko, VS SEM study of the surface of arsenopyrite and pyrite from the Natalkinskoe Deposit, Northeastern Russia. Geochem. Int. 58 (2000) 531–538.
[11] Ballouard C, Poujol M, Mercadier J, Deloule E, Boulvais P, Baele JM, Cuney M, Cathelineau M., Uranium metallogenesis of the peraluminous leucogranite from the Pontivy-Rostrenen magmatic complex (French Armorican Variscan belt): the result of long-term oxidized hydrothermal alteration during strike-slip deformation. Miner Deposita, DOI 10.1007/s00126-017-0761-5., (2017).
[12] Mavrogonatos C, Voudouris P, Berndt J, Klemme S, Zaccarini F, Spry GP, Melfos PG, Tarantola V, Keith A, Klemd M, Haase R., Trace elements in magnetite from the Pagoni Rachi porphyry prospect, NE Greece: Implications for ore genesis and exploration. Minerals, 9(12) (2019) 725.
[13] Jiao W, Yang H, Zhao Y, Zhang H, Zhou Y, Zhang J, Qilai Xie O., Application of trace elements in the study of oil-source correlation and hydrocarbon migration in the Tarim. Ener. Expl. Expl. 28(2010) 451-466.
[14] Li D, Li R, Zhu Z, Xu F., Elemental characteristics of lacustrine oil shale and its controlling factors of the palaeo-sedimentary environment on oil yield: a case from Chang 7 oil layer of Triassic Yanchang Formation in southern Ordos Basin. Acta Geochim, 37(2) (2018) 228-243.
[15] Graham EG, Kelley DK, Slack FJ, Koenig AE., Trace elements in Zn-Pb-Ag deposits and related stream sediments, Brooks Range Alaska, with implications for Tl as a pathfinder element. Geochem. Expl. Env. Anal. 9(2009) 19-37.
[16] Wang GJ, Cheng TJ, Wang DY., Experimental study on trace element method in surface geochemical prospecting for oil and gas. Petroleum Geology & Experiment (in Chinese with English abstract), 27(5) (2005) 544-549.
[17] Tang YP, Li DM, Chen JY, Wang GJ, Chen TJ ., The application of trace elements to geochemical exploration for oil and gas. Geophy. Geochem. Expl. 32 (2008) 350-353.
[18] Singh R, Kumar M, Venkatesh SA, Kurakalva MR, Syed HT, Reddy SGA., Assessment of potentially toxic trace elements contamination in groundwater resources of the coal mining area of the Korba Coalfield, Central India. Env. Earth Sci., 76(2017) 16. DOI 10.1007/s12665-017-6899-8
[19] Mandeng BPE, Bidjeck BML, Ekoa-Bessa AZ, Ntomb DY, Wadjou WJ, Doumo EPE, Bitom DL Contamination and risk assessment of heavy metals, and uranium of sediments in two watersheds in Abiete-Toko gold district, Southern Cameroon. Heliyon, https://doi.org/10.1016/j.heliyon.2019.e02591 ., (2019).
[20] Tehna N, Sababa E, Ekoa-Bessa ZA, Etame J Mine Waste and Heavy Metal Pollution in Betare-Oya Mining Area (Eastern Cameroon). Env. Earth Sci. Res. J. 6 (2019) 167-176.
[21] Cullers RL., The geochemistry of shales, siltstones, and sandstones of Pennsylvanian-Permian age, Colorado, USA: implications for provenance and metamorphic studies. Lithos, 51(2000) 181-203.
[22] Bhuiyan HAM, Rahman JJM, Dampare SB, Suzuki S (2011) Provenance, tectonics and source weathering of modern fluvial sediments of the Brahmaputra-Jamuna River, Bangladesh: Inference from geochemistry. J. Geochem. Expl. 111(2011) 113-137.
[23] Hofer G, Wagreich M, Neuhuber S ., Geochemistry of fine-grained sediments of the upper Cretaceous to Paleogene Gosau Group (Austria, Slovakia): Implications for paleoenvironmental and provenance studies. Geosci. Front. 4(2013) 449-468.
[24] Sharma A, Sensarma S, Kumar K, Khanna PP, Saini KN., Mineralogy and geochemistry of the Mahi River sediments in tectonically active western India: Implications for Deccan large igneous province source, weathering, and mobility of elements in a semi-arid climate. Geochim. Cosmochim. Acta, 104 (2013) 63-83.
[25] Tripathy RG, Singh KS, Ramaswamy V., Major and trace element geochemistry of Bay of Bengal sediments: Implications to provenances and their controlling factors. Palaeogeogr. Palaeoclimatol Palaeoecol. 397 (2014) 20-30.
[26] Bertrand S, Hughen, AK, lveda SJ, Pantoja S Geochemistry of surface sediments from the fjords of Northern Chilean Patagonia (44-47oS): Spatial variability and implications for paleoclimate reconstructions., Geochim. Cosmochim. Acta, 76(2012) 125-146.
[27] Rashid AS, Ganai AJ, Masoodi A, Khan AF., Major and trace element geochemistry of lake sediments, India: implications for weathering and climate control. Arab. J. Geosci. 8(2014) DOI 10.1007/s12517-014-1639-9.
[28] Bhatia MR., Rare earth element geochemistry of Australian Paleozoic graywackes and mudrocks: Provenance and tectonic control. Sediment. Geol. 45 (1985) 97-113.
[29] Bhatia MR, Crook KA., Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins Contrib. Mineral. Petrol. 92 (1986) 181-193.
[30] Armstrong-Altrin JS, Verma SP., Critical evaluation of six tectonic setting discrimination diagrams using geochemical data of Neogene sediments from known tectonic settings. Sediment. Geol., 177 (2005) 115-129.
[31] Hu JJ, Li Q, Li J, Huang J, Ge DS Geochemical characteristics and depositional environment of the Middle Permian mudstones from central Qiangtang Basin, northern Tibet. Geol. J. 51(2016) 560–571.
[32] Bokanda EE, Fralick P, Ekomane E, Njilah IK, Bisse SB, Akono DF, Ekoa-Bessa AZ Geochemical characteristics of shales in the Mamfe Basin, South West Cameroon: Implication for depositional environments and oxidation conditions. J. Afr. Earth Sci. https://doi.org/10.1016/j.jafrearsci.2018.08.004., (2018).
[33] Tchouatcha SM, Tamfuh, AP, Sobdjou, KC, Mbesse, OC, Ngnotue, T., Provenance, palaeoweathering and depositional environment of the cretaceous deposits from the Babouri-Figuil and Mayo Oulo-Lere basins (North-Cameroon) during the Southern Atlantic opening: Geochemical constraints. J. Afr. Earth Sci. https://doi.org/10.1016/j.jafrearsci.2020.104052., (2021).
[34] Guiraud R, Maurin JC ., Early Cretaceous rifts of Western and Central Africa: an overview. Tectonophy, 213(1992) 153-168.
[35] Abolo NJA, Ngos III S, Ondoa BDA, Garcia B Fernanda-Sarmiento, M., Mbesse, O.C., Abolo MG, Eloung-Nna MD, Nkengfack EA, Ndjeng E, Qian, J (2014) Geochemical characterization and mineralogy of Babouri-Figuil Oil Shale, North-Cameroon. J. Surf. Eng. Mat. Advan.Techn. 4 (2014) 359-368.
[36] Schwoerer P ., Carte géologique du Cameroun au 1/500000, coupure de Garoua Est et notice d’explication. Direction des Mines et de la Géologie., (1962).
[37] Hervieu J L., existence de deux cycles climato-sédimentaire dans les monts Mandara et leurs abords (Nord-Cameroun). Conséquences morphologiques et pedogenétiques. C.R. Ac.Sc.L.264.serie D (1967) 2624-2627.
[38] Hervieu J., Le quaternaire du nord-Cameroun Schéma d’évolution géomorphologique et relations avec la pédogenèse. Cahier. O.R.S.T.O.M., sér. I’édol., 8(3) (1970).
[39] Ondoa BDA, Ngos III S, Ndjeng E, Abolo NJA, N’Nanga A., Contribution of the magnetic susceptibility to the characterization of the Babouri-Figuil Cretaceous Basin. Open J. Soil Sci. 4(2014) 272-283.
[40] Ngounouno I, Déruelle B, Guiraud R, Vicat PJ Magmatismes tholéiitique et alcalin des demi-grabens crétacés de Mayo Oulo-Léré et de Babouri-Figuil (Nord du Cameroun–Sud du Tchad) en domaine d’extension continentale. C. R. Acad. Sci. Paris, 333 (2001) 201-207.
[41] Maurin JC, Guiraud R., Relationships between tectonics and sedimentation in the Barremo-Aptian intracontinental basins of Northern Cameroon., J. Afr. Earth Sci., 10(1990) 331-340.
[42] Maurin JC, Guiraud R ., Basement control in the development of the Early Cretaceous West and Central African Rift System. Tectonophy. 228 (1993) 81-95.
[43] Toteu SF, Michard A, Bertrand JM, Rocci, G U-Pb Dating of Precambrian Rocks from Northern Cameroon, Orogenic Evolution and Chronology of Pan-African Belt of Central Africa. Precambrian Res. 37 (1987) 71-87. https://doi.org/10.1016/0301-9268(87)90040-4
[44] Taylor SR, McLennan SM., The continental crust: Its composition and evolution. Blackwell, Oxford, (1985) 312.
[45] Haskin LA, Haskin MA, Frey FA, Wildman TR Relative and absolute terrestrial abundances of the rare piles of earth. In: Ahrens, L.H. (Ed.), Origin and distribution of the elements. Oxford: Pergamon, (1968) 889-912.
[46] Eltom HA, Abdullatif OM, Makkawi MH., Rare earth element geochemistry of shallow carbonate outcropping strata in Saudi Arabia: application for depositional environments prediction. Sediment. Geol. 348(2017) 51-68.
[47] Allègre C, Michard G., Introduction to Geochemistry (Geophysics and Astrophysics Monographs). 10, D. Reidel Publishing Company, Boston, USA, 143(1974).
[48] Floyd PA, Leveridge BE., Tectonic environment of the Devonian Gramscatho basin, South Cornwall: framework mode and geochemical evidence from turbidite sandstones. J. Geol. Soc.144(1987) 531-542.
[49] Etemad-Saeed N, Hosseini-Barzi M, Armstrong-Altrin JS (2011) Petrography and geochemistry of clastic sedimentary rocks as evidence for the provenance of the Lower Cambrian Lalun Formation, Posht-e-badam block, central Iran. J. Afr. Earth Sci. 61(1987) 142-159.
[50] Nagarajan R, Armstrong-Altrin JS, Nagendra R, Madhavaraju J, Moutte J., Petrography and geochemistry of terrigenous sedimentary rocks in the Neoproterozoic Rabanpalli formation, Bhima Basin, northern Karnataka, Southern India: implications for paleoweathering condition, provenance, and source rocks composition. J. Geol. Soc. India, 70(2007) 297-312.
[51] Ngueutchoua G, Eyong TJ, Ekoa-Bessa AZ, Agheenwi ABZ, Maschouer EA, Kemteu SC, Dzoti LY, Hamadou T, Baboule MOB, Nguemo KG Provenance and depositional history of Mesozoic sediments from the Mamfe basin and Douala sub-basin (SW Cameroon) unraveled by geochemical analysis, J. Afr. Earth Sci. 158 (2019) 103550.
[52] Garver JI, Royce PR, Smick AT., Chromium and nickel in the shale of the Taconic foreland: a case study for the provenance of fine-grained sediments with an ultramafic source. J. Sediment. Res. 100 (1996) 100-106.
[53] Cullers RL., Mineralogical and chemical changes of soil and stream sediment formed by intense weathering of the Danburg granite, Georgia, U.S.A. Lithos, 21(1988) 301-314.
[54] Ganwa AA, Frisch W, Siebel W, Ekodeck EG, Shang, KC, Ngako V., Archean inheritances in the pyroxene-amphibole-bearing gneiss of the Méiganga Area (Central North Cameroon):
Geochemical and 207Pb/206Pb age imprints. C. R. Geosci. 340 (2008) 211-222.
[55] Ganwa AA, Klotzli SU, Hauzenberger C Evidence for Archean inheritance in the pre-Panafrican crust of Central Cameroon: Insight from internal zircon structure and LA-MC-ICP-MS U-Pb ages. J. Afr. Earth Sci. 120 (2016) 12-22.
[56] Hatch JR, Leventhal JS., Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian (Missourian) stark shale member of the Dennis Limestone, Wabaunsee County, Kansas, USA. Chem. Geol. 99(1992) 65-82.
[57] Jones B, Manning DAC., Comparison of geochemical indices used for the interpretation of palaeoredox conditions in ancient mudstones. Chem. Geol. 111(1994) 111-129.
[58] Mao LJ, Mo DW, Yang JH, Guo YY, Lv HY Rare earth elements geochemistry in surface floodplain sediments from the Xiangjiang River, the middle reach of Changjiang River, China. Quater. Int. 336 (2014) 80-88.
[59] Zhao BS, Li RX, Wang XZ, Wu XY, Wang N, Qin, XL, Cheng JH, Li JJ ., Sedimentary environment and preservation conditions of organic matter analysis of Shanxi formation mud dshale in Yanchang exploration area, Ordos Basin. Geol Sci Technol Inf ((in Chinese with English abstract), 35(6) (2016) 103-111.
[60] Xu QL, Liu B, Ma YS, Song XM, Wang YJ, Chen ZX., Geological and geochemical characterization of lacustrine shale: A case study of the Jurassic Da'anzhai member shale in the central Sichuan Basin, southwest China. J. Nat. Gas Sci. Eng. 47 (2017) 124-139.
[61] Teng GE, Hui LW, Xu YC, Chen JF ., Correlative study on parameters of inorganic geochemistry and hydrocarbon source rocks formative environment. Adv. Earth Sci. (in Chinese with English abstract), 20(2) (2005) 193-200.
[62] Roy DK, Roser BP., Climatic control on the composition of Carboniferous-Permian Gondwana sediments, Khalaspir basin, Bangladesh. Gondwana Res. 23 (2013) 1163-1171.
[63] Sarki-Yandoka BM, Abdullah WH, Abubakar MB, Hakimi MH, Adegoke AK., Geochemical characterization of Early Cretaceous lacustrine sediments of Bima Formation, Yola sub-basin, Northern Benue trough, NE Nigeria: Organic matter input, preservation, paleoenvironment and palaeoclimatic conditions. Mar. Petrol. Geol. 61 (2015) 82-94.
[64] Wang YY, Wu P., Geochemical criteria of sediments in the coastal area of Jiangsu and Zhejiang Provinces. J Tongji Univ (Nat Sci) (in Chinese with English abstract) 4 (1983) 82-90.
[65] Ndjigui JD, Onana LV, Sababa E, Bayiga CE Mineralogy and geochemistry of the Lokoundje alluvial clays from the Kribi deposits, Cameroonian Atlantic coast: Implications for their origin and depositional environment. J. Afr. Earth Sci.143 (2018) 102-117.
[66] Cullers RL., The chemical signature of source rocks in size fractions of Holocene stream sediment derived from metamorphic rocks in the Wet Mountains region, Colorado, U.S.A. Chem. Geol. 113 (1994) 317-343.
[67] Teng GE, Liu WH, Xu YC., Identification of effective source rocks of Ordovician marine sediments in Ordos Basin. Prog. Nat. Sci. (in Chinese), 14(11) (2004) 1249-1252.
[68] Liu J, Yao YB, Elsworth D, Pan ZJ, Sun XX, Ao WH., Sedimentary characteristics of the Lower Cambrian Niutitang shale in the southeast margin of Sichuan Basin, China. J. Nat. Gas Sci. Eng. 36 (2016) 1140-1150.
[69] Cullers RL, Podkovyrov NV., Geochemistry of the Mesoproterozoic Lakhanda shales in southeastern Yakutia, Russia: Implications for mineralogical and provenance control, and recycling. Precambrian Res.104(2000) 77-93.