Investigation of the Moisture Diffusion Process in Fibre- Reinforced Composites by Studying the Diffusivities in Hot-wet Temperature Resin-matrix
International Journal of Mechanical Engineering |
© 2014 by SSRG - IJME Journal |
Volume 1 Issue 2 |
Year of Publication : 2014 |
Authors : Sridhar Sathyanarayanan |
How to Cite?
Sridhar Sathyanarayanan, "Investigation of the Moisture Diffusion Process in Fibre- Reinforced Composites by Studying the Diffusivities in Hot-wet Temperature Resin-matrix," SSRG International Journal of Mechanical Engineering, vol. 1, no. 2, pp. 7-12, 2014. Crossref, https://doi.org/10.14445/23488360/IJME-V1I2P102
Abstract:
Moisture diffusion or uptake is one of the phenomenon observed in fibre reinforced composites exposed to marine ambience or water body structures. The materials are exposed to variations in temperatures and humidity. Moisture uptake depends upon the nature of the resin, porosity, temperature, humidity, salt water concentrations, fibre orientation, fibre volume fraction, void content, resin matrix interface, interfacial bonding. Moisture is known to react with one or more of the matrix constituents and hydrolyses the polymer bonds which leads to dissolution of water-soluble molecules and thereby plasticizing the matrix and lowering the glass transition temperature (Tg). Moisture absorption produces debonding of the fibre matrix interface and thus deteriorates the mechanical properties of the composites. It also causes swelling of the matrix phase and weakening/breaking of the matrix/fibre bond, formation of micro-cracks due to environmental stresses and polymer-solvent interactions. Hence the rate of deterioration is governed by the rate of moisture absorption and percentage of moisture content present. This affects the short-term and long-term durability of the composites. Hence determination of moisture content and rate of moisture diffusion is necessary to understand the kinetics of moisture diffusion. In this study three types of Fibre reinforced composites,glassfibre/polyester, glassfibre/vinylester and glassfibre/epoxy resin laminates are fabricated by Hand lay-up process and compacted in a Hotpress.An experiment is performed to compute the diffusion co-efficients at different times in hot-wet temperature of different fibre/resin combinations and theoretically evaluated by Fick’s law of diffusion.
Keywords:
Diffusivity, Hand lay-up, Hotpress, Moisture diffusion, resin.
References:
1. M Nakada Y Miyano, Material System Research Laboratory, Kanazawa Institute Of Technology, 16 th Int.Conf.of Composite Materials.[1]
2. A Naceri. Laboratory of materials, Faculty of Sciences and Engineering, University of M’sila, Algeria.
3. Mei Lei, Temperature and moisture effects on Composite Materials for wind turbine blades, Montana State University, Bozemon, Montana, March 2000.
4. G.Czel and T Czigany,”A study of water absorption and mechanical properties of glassfibre/polyester composite pipes- Effects of specimen geometry and preparation,” journal of composite materials, Vol.42,(2008) pp.2815-2827.
5. Pritchard G, Speakes D,”The use of water absorption kinetic data to predict laminate property changes,” Composites, Vol.18,(1987) pp.227-232.
6. Chin JW, Aoudi and Nguyen, “Effect of environmental exposure on fibre reinforced plastics(FRP) Materials used in construction,” journal of composites technology and research, JCTRER, Vol.19,Issue 4,(1997),pp.205-213.
7. Hyeong Yeol Kim, Young Hawn Park, Young Jun You, Chang Kwon Moon,”Short term durability test for GFRP rods under various environmental conditions,” Composite structures, Vol.83(2008),pp.37-47.
8. Pilli SP, Simmons KL, Holbery JD, Shuttinandan V, Stickler PB and Smith LV,” A novel accelerated moisture absorption test and characterization,” Composites Part-A; Applied science and manufacturing, Vol.40, Issue 9(2009), pp.1501-1505.
9. Caeter HG, Kibler KG, Langmuir,”Type model for anamolous moisture diffusion in composite resins,” journal of composite materials, Vol.12,(1978),pp.118-131.
10. http://www.spsystems.com/
11. http://www.gurit.com/
12. Dewimille B,Bunsell AR,”Accelerated ageing of glass fibre reinforced epoxy resin in water,” Composites, Vol.14, Issue 1(1983), pp.35-40.
13. Chin JW, Nyugen T and Aoudi K,”Sorption and diffusion of water,salt water and concrete pore solution in composite matrices,” journal of Applied polymer science, Vol.71,(1999),pp.483-492.