Microstructural and Corrosion Aspects of Aluminium-Zirconia Metal Matrix Composites in Acidic Condition

International Journal of Mechanical Engineering
© 2019 by SSRG - IJME Journal
Volume 6 Issue 11
Year of Publication : 2019
Authors : S.Roseline, Dr.V.Paramasivam
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S.Roseline, Dr.V.Paramasivam, "Microstructural and Corrosion Aspects of Aluminium-Zirconia Metal Matrix Composites in Acidic Condition," SSRG International Journal of Mechanical Engineering, vol. 6,  no. 11, pp. 19-23, 2019. Crossref, https://doi.org/10.14445/23488360/IJME-V6I11P104

Abstract:

Aluminum (Al6061) reinforced with ZrO2 was fabricated using stir casting techniques. In the present study, this composite's corrosion behavior was investigated with 0, 5, 10, and 15 vol% of ZrO2. This work investigates the corrosion rates of Al6061-ZrO2 composites by weight loss and electrochemical polarization methods. In the weight-loss method, the base metal and its composites were immersed in 0.1M hydrochloric acid (HCl) solution for 480 hours, periodically measuring the losses in weight. The composite was immersed in a 0.1M HCl solution in the electrochemical polarization method, and its corrosion parameters such as corrosion potential (Ecorr) and corrosion current (Icorr) were evaluated. In both weight loss and polarization methods, the corrosion rate of Al6061 was found to be more than the composites, and the composite with 15 vol% of zirconia had the least corrosion rate. The surface morphology of Aluminum before and after corrosion was investigated using scanning electron microscopic images (SEM). Before corrosion, the results showed that ZrO2 particles were finely distributed in the matrix with a little agglomeration in some areas. The microscopic images after corrosion revealed very deep pits in Al6061 alloy. The pits were seen as shallow as the volume % of reinforcement increased.

Keywords:

metal matrix composite, stir casting, corrosion, weight-loss method, electrochemical polarization, microstructure.

References:

[1] "Study of corrosion resistance of Aluminum alloy 6061/SiC composites in 3.5% NaCl solution", Muna K.Abbass, Khairia S.Hassan, and AbbasS. Alwan, International Journal of Materials, Mechanics and Manufacturing, 3. 2015.
[2] "Carbon network/aluminum composite made by powder metallurgy and its corrosion behavior in seawater," Yong X. Gan, Joseph Dong, Jeremy B. Gan, Materials chemistry and physics, 202,2017,190-196.
[3] "Study of corrosion of Al-Cu hypoeutectic alloys and Al-Cu composite fabricated using stir casting technique," P. Vijaya Kumar Raju, K. Anji Reddy, J. BabuRao, NRMR Bhargava, M. Indra Reddy, and Materials Today: Proceedings, 5, (2018), 1776–1784.
[4] "Corrosion behavior of aluminum base particulate metal matrix composites: A review," Ajay SinghVerma, Sumankant, Narender Mohan Suri, Yashpal, Materials Today: Proceedings 2 (2015) 2840 – 2851.
[5] "Corrosion behavior of magnesium-graphene composites in sodium chloride solutions" Muhammad Rashad, Fusheng Pan, Muhammad Asif, Xianhua Chen, Journal of Magnesium and Alloys 5 (2017) 271–27.
[6] "Latest research development in the aluminum matrix with particulate reinforcement composites a review," A.Thirumoorthy, T. V. Arjunan, K. L. Senthil Kumar Materials Today: Proceedings 5 (2018) 1657–1665.
[7] "Fabrication and corrosion resistance of a graphene-tin oxide composite film on Aluminum alloy 6061", Linghui Yang, Yunxiao Wan, Zhenlan Qin, QunjieXu, YulinMin, Corrosion Science130 (2018)85–94.
[8] "Corrosion behavior of a quenched and partitioned medium carbon steel in3.5 wt. NaCl solution", Jilan Yang, Yufei Lu, Zheng hong Guo, Jianfeng Gu, Caixiang Gu, Corrosion Science 130 (2018) 64–75.
[9] "Corrosion behavior of electrodeposited nanocrystalline nickel-iron (NiFe) alloys in dilute H2SO4", Leo Monaco, Gordana Avramovic-Cingara, Gino Palumbo, Uwe Erbm Corrosion Science 130 (2018) 103-112.
[10] "Corrosion of mild steel at the seawater/sediments interface: Mechanisms and kinetics," Ph. Refait, A. -M. Grolleau, M. Jeannin, E. François, R. Sabot Corrosion Science 130 (2018) 76–84.
[11] "An investigation of mechanical properties and corrosion resistance of Al2618 alloy reinforced with Si3N4", AlN and ZrB2 composites, N.MathanKumar, S.SenthilKumaran, L.A.Kumara swamidhas, Journal of Alloys and Compounds652(2015)244-249
[12] S.Vijayakumar, M.Soundarrajan, S.Palanisamy and K.Pasupathi, "Studies on Mechanical Properties of Al-Sic Metal Matrix Composite" SSRG International Journal of Material Science and Engineering 2.3 (2016): 1-5.
[13] "Investigation of corrosion behavior of lightweight Nano Hybrid Al6061-ZrO2–SiC-Gr composites", P.R.Thyla, N.Tiruvenkadam, M.SenthilKumar, International Journal of Chem Tech Research,8, (2015)312-316.
[14] "Tensile and fracture behavior of nano/micro TiB2 particle reinforced casting A356 aluminum alloy composites", M.Karbalaei, Akbari, H.R.Baharvandi, K.Shirvanimoghaddam, Materials and Design, 6, (2015), 150-161.
[15] "TiB2 reinforced aluminum based in situ composites fabricated by stir casting", Fei Chen, Zongning Chen, Feng Mao, Tongmin Wang, Zhiqiang Cao, Materials Science, and Engineering A, 625, (2015), 357-368.
[16] "Prediction of influence of process parameters on tensile strength of AA6061/TiC aluminum matrix composites produced using stir casting", J. Jebeenmoses, I.Dinaharan, S. Josephsekhar, and Transactions of Nonferrous Metals Society of China, 26, (2016), 1498-1511.
[17] "Electrochemical corrosion behavior of Pb-Ca-Sn-Sm grid alloy in H2SO4 solution", SadeghPour-Ali, Mohammad Mosallami Aghili, Ali Davoodi, Journal of Alloys and Compounds, 652(2015)172-178