Synthesis and Characterization and of transition metal (II) Complexes of 1-(3, 5-bis(tri fluoromethyl) phenyl -4-4-4-trifluerobutane-1,3-dione
International Journal of Applied Chemistry |
© 2020 by SSRG - IJAC Journal |
Volume 7 Issue 1 |
Year of Publication : 2020 |
Authors : Madhukar P.Shinde, Raghunath B.Toche, Pankaj B.Aware, Satish M. Chvan |
How to Cite?
Madhukar P.Shinde, Raghunath B.Toche, Pankaj B.Aware, Satish M. Chvan, "Synthesis and Characterization and of transition metal (II) Complexes of 1-(3, 5-bis(tri fluoromethyl) phenyl -4-4-4-trifluerobutane-1,3-dione," SSRG International Journal of Applied Chemistry, vol. 7, no. 1, pp. 69-76, 2020. Crossref, https://doi.org/10.14445/23939133/IJAC-V7I1P114
Abstract:
Cu(II); Mn(II), Ni(II) and Co(II) complexes of (1-(3,5-bis(tri fluoromethyl) phenyl -4-4-4-trifluerobutane-1,3-dione derived from 3,5-bis-trifluoromethyl acetophenone and trifluoroacetate have been synthesized and characterized by elemental analysis, FTIR, UV-Visible spectroscopy, and TG-DTA . The UV spectra showed that the ligand form square planar complex with Cu(II) while it forms octahedral complexes with Mn(II), Ni(II) and Co(II).
Keywords:
square planar complex, octahedral complexes, trifluerobutane-1,3-diketone,Cu(II); Mn(II), Ni(II) and Co(II) complexes
References:
[1] K.L. Krishnakumar and Mathew Paul, Metal complexes of heterocyclic unsaturated 1, 3- diketones IJPSR, 2013; Vol. 4(3): 1154-1158 1,3-Diketones. Synthesis and Properties, E. A. Shokova, J. K. Kim, and V. V. Kovalev
[2] Kel’in, A.V., Curr. Org. Chem., 2003, vol. 7, no. 16, p. 1691. , Kel’in, A.V. and Maioli, A., Curr. Org. Chem., 2003, vol. 7, no. 18, p. 1855.
[3] Shchegol’kov, E.V., Burgart, Ya.V., Khudina, O.G., Saloutin, V.I., and Chupakhin, O.N., Russ. Chem. Rev., 2010, vol. 79, no. 1, p. 31.
[4] Isakova, V.G., Khlebnikova, T.S., and Lakhvich, F.A., Russ. Chem. Rev., 2010, vol. 79, no. 10, p. 849.
[5] Zolotareva, N.V. and Semenov, V.V., Russ. Chem. Rev., 2013, vol. 82, no. 10, p. 964.
[6] Bonne, D., Coquerel, Y., Constantieux, T., and Rodriguez, J., Tetrahedron: Asymmetry, 2010, vol. 21, p. 1085.
[7] Colombo, M. and Peretto, I., Drug Discovery Today, 2008, vol. 13, p. 677.
[8] Hulme, C. and Gore, V., Curr. Med. Chem., 2003, vol. 10, p. 51.
[9] Simon, C. and Rodriquez, T., J. Org. Chem., 2004, vol. 24, p. 4957.
[10] Berkessel, M Bolte, T Neumann, and L Seidel. (1996). Synthesis and X-ray crystal structure of the first mononuclear nickel(II) alkane thiolate complex with a mixed (S,N,N,O) ligand field. Chem Ber 129:1183–1189.
[11] JR Lancaster. The Bioinorganic Chemistry of Nickel. New York: Wiley-VCH; (1988).
[12] AF Kolodziej. (1994). The chemistry of nickel containing enzymes. Prog Inorg Chem 41:493–597.
[13] RK Parashar, RC Sharma, A Kumar, and G Mohan. (1988). ―Stability studies in relation to IR data of some Schiff base complexes of transition metals and their
biological and pharmacological studies‖. Inorg Chim Acta 151:201–208.
[14] DX West, H Gebremedhin, RJ Butcher, JP Jasinski, and AE Liberta. (1993). ―Structures of nickel(II) and copper(II) complexes of 2-acetylpyridine azacyclothiosemicarba zones‖. Polyhedron 12:2489–2497.
[15] M Beley, JP Collin, R Rupert,and JP Sauvage. (1986). ―Electrocatalytic reduction of CO2 by Ni(cyclam)2+ in water. Study of the factors affecting the efficiency and the selectivity of the process”. J Am Chem Soc 108:7461–7467.
[16] E Fujita, BS Brunschwig, T Ogata,and S Yanagida. (1994). ―Toward photochemical carbon dioxide activation by transition metal complexes‖. Coord Chem Rev 132:195–200.
[17] E Kimura, S Wada, M Shionoya, and Y Okazaki. (1994). ―New series of multi functionalized nickel(II)-cyclam complexes. Application to the photoreduction of carbon dioxide‖. Inorg Chem 33:770–778.
[18] A. Chakraborty, P. Kumar, K. Ghosh, and P. Roy, ―Evaluation of a Schiff base copper complex compound as potent anticancer molecule with multiple targets of action,‖ European Journal of Pharmacology, vol. 647, no. 1–3, pp. 1–12, 2010.
[19] R. H. Holm, P. Kennepohl, and E. I. Solomon, ―Structural and functional aspects of metal sites in biology,‖ Chemical Reviews, vol. 96, no. 7, pp. 2239–2314, 1996.
[20] M. A. Ali, C. M. Haroon, M. Nazimuddin, S. M. M.-U. Majumder, M. T. H. Tarafder, and M. A. Khair, ―Synthesis, characterization and biological activities of some new nickel(II), copper(II), zinc(II) and cadmium(II) complexes of quadridentate SNNS ligands,‖ Transition Metal Chemistry, vol. 17, no. 2, pp. 133–136, 1992.
[21] D. T. Minkel, C. H. Chanstier, and D. H. Petering, ―Reactions of 3-Ethoxy-2-oxobutyraldehyde Bis(N4-dimethylthiosemicarbazonato)-Zinc(II) with tumor cells and mitochondria,‖ Molecular Pharmacology, vol. 12, no. 6, pp. 1036–1044, 1976.
[22] V. Rajendiran, R. Karthik, M. Palaniandavar et al., ―Mixed-ligand copper(II)-phenolate complexes: effect of coligand on enhanced DNA and protein binding, DNA cleavage, and anticancer activity,” Inorganic Chemistry, vol. 46, no. 20, pp. 8208–8221, 2007.
[23] A. E. Liberta and D. X. West, ―Antifungal and antitumor activity of heterocyclic thiosemicarbazones and their metal complexes: current status,‖ Biometals, vol. 5, no. 2, pp. 121–126, 1992.
[24] Y. Harinath, D. H. K. Reddy, B. N. Kumar, C. Apparao, and K. Seshaiah, ―Synthesis, spectral characterization and antioxidant activity studies of a bidentate Schiff base, 5-methyl thiophene-2-carboxaldehyde-carbohydrazone and its Cd(II), Cu(II), Ni(II) and Zn(II) complexes,” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 101, pp. 264–272, 2013.
[25] J. Sheikh, H. Juneja, V. Ingle, P. Ali, and T. B. Hadda, ―Synthesis and in vitro biology of Co(II), Ni(II), Cu(II) and Zinc(II) complexes of functionalized beta-diketone bearing energy buried potential antibacterial and antiviral O,O pharmacophore sites,” Journal of Saudi Chemical Society, vol. 17, no. 3, pp. 269–276, 2013.
[26] Rosslenbroich, H.J.; Stuebler, D. Botrytis cinerea—History of chemical control and novel fungicides for its management. Crop Prot. 2000, 19, 557–561
[27] Chunhui Liu , Zining Cui ,, Xiaojing Yan , Zhiqiu Qi , Mingshan and Xinghai Li, Synthesis, Fungicidal Activity and Mode of Action of 4-Phenyl-6-trifluoromethyl-2-minopyrimidines; against Botrytis cinerea, Molecules 2016, 21, 828; doi:10.3390/molecules21070828
[28] Rashd M El-Ferjani ,Musa Ahmed ,Farah Wahida Harun, Bulgasem Y Bulgasem, vol 10(6), ver.I,6-13
[29] Kaber A. Shaikh and Khaled Shaikh, Candian chemical Transitions, 2015,vol.3(2),207-224.