Development of Green and Polymer-supported Periodates forms of Amberlyst a 26 and Amberlite IRA 904 for oxidation of 1-Phenyl alcohol

International Journal of Applied Chemistry

© 2023 by SSRG - IJAC Journal

Volume 10 Issue 1

Year of Publication : 2023

Authors : Vilas Sonawane

10.14445/23939133/IJAC-V10I1P101

How to Cite?

Vilas Sonawane, "Development of Green and Polymer-supported Periodates forms of Amberlyst a 26 and Amberlite IRA 904 for oxidation of 1-Phenyl alcohol," SSRG International Journal of Applied Chemistry, vol. 10,  no. 1, pp. 1-4, 2023. Crossref, https://doi.org/10.14445/23939133/IJAC-V10I1P101

Abstract:

The periodate forms of some commercial macroporous anion-exchange resins can be used in either protic or aprotic solvents to oxidize various quinols, catechols, and glycols and also triphenylphosphine, hydrazobenzene, and benzohydroxamic acid. The reagents in methanol oxidize thioethers. Polymer-supported iodate also oxidizes quinols and catechols. The periodate anion oxidizes various functional groups, but the solubility properties of sodium and potassium periodates are such that these salts can generally be used only in hydroxylic media [1,2]. Reactions can be carried out in aprotic solvents by using periodic acid [3], sodium periodate supported on silica gel [4] or certain lipophilic quaternary ammonium salts [5,6]. We wish to report that the periodate forms of some macroporous anion exchange resins, which can be considered polymer-supported quaternary ammonium periodates, are a practically useful alternative. We have shown that they can be used in various solvents, including aprotic solvents, to oxidize various quinols, catechols, glycols, and triphenylphosphine, hydrazobenzene, and benzohydroxamicacid. Polymer-supported iodate also oxidizes quinols and catechols [7,8]. The periodate forms of Amberlyst A26 and Amberlite IRA 904, two commercial macroporous anion exchange resins, and the iodate form of Amberlyst A 26 were prepared by standard ion-exchange procedures. The dried reagents generally contained 1.2 -1.9 mmol of oxidant per g. The products of reactions with these reagents were isolated simply by filtering off the resin and evaporating the solvent from the filtrate. In many cases, the residue was essentially a pure product. Some reactions produced small amounts of iodine, but this was readily sublimed from the products.

Keywords:

Periodates, Amberlyst A 26, Amberlite IRA 904, Oxidation.

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